Extreme Differences in PTFE Flat Gaskets

The most well-known calendering process is called HS10; it was originally developed by DuPont. In this process, PTFE is sheared and oriented in different directions. The applied shear energy results in fibrillation; the long-chain PTFE molecules intertwine with each other and with the fillers. This structure significantly improves creep behavior and consequently extends the sealing service life. A final sintering process, as described earlier, is mandatory. As this process seeks to provide added structure to the material, it is commonly referred to as ‘structured PTFE’.

The quality of the finished sheets, and ultimately the gaskets manufactured from them, depends on the degree of fibrillation and the type and proportion of the filler used. A higher filler content is desired for better mechanical properties. However, the proportion must be precisely balanced, as the amount of PTFE itself significantly impacts the seal’s tightness. Without careful control of both the material makeup and the structuring process, the desired result (a high degree of fibrillation) is not fully achieved, and the resultant material properties suffer accordingly.

Expanded PTFE Manufacturing Process

Similar to the structured process, in expanded PTFE (or ePTFE for short), PTFE is mixed with a lubricant. Subsequently, the PTFE is compressed into a preform. The purpose of pressing is to remove the present air from the mixture. The preform is then pushed through an extrusion die in an extruder to obtain the desired shape. The extrusion die must be designed to ensure a high degree of fibrillation (interweaving of the long-chain PTFE molecules) in the PTFE occurs. A two-roll calender is then used for calendering the profiles. The calendering process from the profile to the foil is usually carried out in a single operation. The foil is then dried at temperatures between 150°C to 200°C, which completely removes the lubricant.

Next, the foil undergoes a longitudinal stretching process by at least two rotating roller systems operating at different speeds, at a temperature of 250°C to 350°C. Depending on the quality of the paste PTFE resin utilized, the foil can be stretched with a ratio of over 1:10 without the formation of defects. The stretched material becomes highly porous, resulting in a monoaxial alignment.

An additional stretching process in the transverse direction allows the foil layers to acquire a biaxial or multidirectional alignment, forming expanded PTFE membranes. A multidirectional PTFE exhibits uniform fibrillation in all directions, significantly improving its mechanical properties. For multidirectional expanded PTFE sheets, multiple membranes are stacked on top of each other and sintered together at higher temperatures before being further processed.

The thickness of the membrane, homogeneity of stretching, and degree of fibrillation significantly influence the mechanical properties and the tightness of the material. Monoaxially stretched PTFE can be used as sealing tape or sealant. Biaxially or multi-directionally stretched PTFE is available as sealing tape and as sheets.

Comparing Different Models

Comparative studies of different PTFE gaskets can be used to measure the creep re- laxation behavior. The following investigations refer to tests according to EN 13555.

EN 13555, is a popular European test standard that provides several important sealing parameters that assist with the comparison of different materials. The four parameters for meeting the leak tightness requirement are:

• The maximum surface pressure strength of the gasket (above this, the gasket or the flange is destroyed),
• The required minimum surface pressure to achieve the desired tightness (below this, leakage increases),
• The applied surface pressure when installing the gasket,
• The Leakage rates.

These detailed gasket parameters as well as the creep and relaxation properties of the gasket, are key selection criteria for a gasket and are uniformly defined in EN 13555. The determined parameters are subsequently used for torque calculations according to EN 1591-1 and for the classification of PTFE types.

PQR Value (Creep Relation Value)

An important resultant value from EN 13555 testing is the creep-relaxation (PQR) value. The PQR value is determined by assessing the ratio of residual surface pressure to initial surface pressure after a relaxation test conducted in a press using a displacement-controlled load sensor at a specific stiffness. The resultant PQR value can range from 0 to 1.

A PQR value of 1 defines no loss of surface pressure, indicating an extremely high level of creep resistance. If the gasket loses all surface pressure during the test, a PQR value of 0 is obtained. Therefore, a high PQR value is desirable.

PQR Test Results

Image 1 shows the different PQR values of the various PTFE types. The tests were conducted with an initial surface pressure of 30 MPa and temperatures ranging from 25°C to 230°C. The results of the test indicate that the special manufacturing processes of structured PTFE and expanded PTFE consistently result in higher PQR values. The significant advantages of high- quality PTFE become Particularly relevant at temperatures elevated above 100 °C.

Calculations under the same conditions but with differently manufactured PTFE gaskets will result in minimum torque values as shown in Image 2. These minimum torque values are necessary to achieve a tightness class of L0.01 under the given conditions. Applying torque above the maximum torque will damage one of the components (flange, bolt, or gasket).

Typically, for small dimensions, the bolts are the weakest component, while for larger dimensions, the flanges are the weakest. Due to the low PQR value of virgin PTFE, extremely high minimum torque values are required to achieve a consistently tight connection. However, with structured or expanded PTFE, a wider torque range can be obtained. High-quality ePTFE, due to its higher PQR value, offers advantages over structured PTFE, particularly at temperatures above 100 °C.

Conclusion and Practical Tips

These investigations demonstrate the diverse range of PTFE as a material in sealing technology. Raw material quality and manufacturing processes are decisive factors in producing high-quality gasket materials. When combined with appropriate manufacturing expertise, the fundamental material properties of PTFE can be significantly improved. The test results and calculations provide a good assessment of the different materials and confirm practical user experiences:

• Virgin PTFE exhibits significant creep/ cold flow behavior, resulting in a high loss of surface pressure and increased leakage, ultimately leading to joint failure. The range of application conditions for this material is typically limited to mild temperature and pressure.


• To reduce the creep behavior of typical PTFE, structured PTFE incorporates not only fillers but also generates fibrillation through calendaring. This modification raises the safe operating temperature and pressure significantly.


• Insufficient fibrillation, inadequate filler selection, and improper PTFE content are often present in low-cost and poorly made PTFE materials.


• 100% multidirectional ePTFE, particularly for the chemical and pharmaceutical industries, holds the highest value as a gasket made of pure PTFE. The highly- fibrillated material allows for meeting the most demanding requirements in terms of creep stability, maximum surface pressure, and temperature.


• The production of expanded PTFE sheets is by far the most complex process in manufacturing PTFE sheets, requiring a high level of expertise. This explains the significant quality differences between market leaders and other suppliers.

Considerations for designers/engineers:

• There are significant qualitative differences in PTFE that must be considered when selecting a gasket. When in doubt, it is advisable to seek the advice of experts

Considerations for procurement professionals:

• High-quality PTFE resins and other raw materials in the manufacturing process, as well as the cost of manufacturing high-quality, high-performance PTFE sealing materials is not generally cheap. It is important to consider the hidden costs of material purchase price savings.

Considerations for maintenance management:

• PTFE gaskets can significantly increase the service life and quality of equipment and products if the correct project-specific PTFE is chosen.